Gold(I) Complexes Bearing Sterically Imposing, Saturated Six- and Seven-Membered Expanded Ring N-Heterocyclic Carbene Ligands
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https://figshare.com/articles/dataset/Gold_I_Complexes_Bearing_Sterically_Imposing_Saturated_Six_and_Seven_Membered_Expanded_Ring_N_Heterocyclic_Carbene_Ligands/2515528
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资源简介：
The synthesis and characterization of novel six- and
seven-membered
expanded ring N-heterocyclic carbene (NHC) complexes of the general
formula [Au(NHC)Cl] are described. The key structural parameters of
complexes 1, 2, and 4 have
been evaluated by solid-state analysis and by means of the percent
buried volume (%Vbur) analysis. Complex 4 is found to demonstrate the largest %Vbur value of any gold(I) NHC complex reported to date, with
a value of 52.6. All complexes 1–4 have been evaluated in a preliminary catalytic survey of the hydration
of internal alkynes.
创建时间：
2012-06-11
