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Dehydrative Thiolation of Allenols: Indium vs Gold Catalysis

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Figshare2016-02-15 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Dehydrative_Thiolation_of_Allenols_Indium_vs_Gold_Catalysis/2208508
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Intermolecular additions of thiols to allenols via formal SN2′ selectivity to produce functionalized dienes are described. Although this dehydrative reaction was initially developed using gold­(I) catalysis, indium­(III) proves to be a far superior catalyst in terms of selectivity and substrate scope.
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2016-02-15
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