New Initiation Modes for Directed Carbonylative C–C Bond Activation: Rhodium-Catalyzed (3 + 1 + 2) Cycloadditions of Aminomethylcyclopropanes
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https://figshare.com/articles/dataset/New_Initiation_Modes_for_Directed_Carbonylative_C_C_Bond_Activation_Rhodium-Catalyzed_3_1_2_Cycloadditions_of_Amino_methyl_cyclo_propanes/3993627
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资源简介：
Under carbonylative conditions, neutral
Rh(I)-systems modified
with weak donor ligands (AsPh3 or 1,4-oxathiane) undergo
N-Cbz, N-benzoyl, or N-Ts directed insertion into the proximal C–C
bond of aminomethylcyclopropanes to generate rhodacyclopentanone
intermediates. These are trapped by N-tethered alkenes to provide
complex perhydroisoindoles.
创建时间：
2016-10-13
