Dinitrogen Complexes of Pincer-Ligated Iridium
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https://figshare.com/articles/dataset/Dinitrogen_Complexes_of_Pincer_Ligated_Iridium/3049732
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资源简介：
Precursors of the fragment (PCP)Ir have been
previously reported to react with dinitrogen to give the bridging
dinuclear complex [(PCP)Ir]2(N2) (2), which was crystallographically characterized. We report that under N2 atmosphere
the only observable nitrogen complex in solution is actually
the terminal dinitrogen complex (PCP)Ir(N2). The mono- and
dinuclear species are in equilibrium; the dinuclear complex
more readily crystallizes from solution.
创建时间：
2006-11-06
