Dinitrogen Complexes of Pincer-Ligated Iridium
收藏NIAID Data Ecosystem2026-03-06 收录
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Precursors of the fragment (PCP)Ir have been previously reported to react with dinitrogen to give the bridging dinuclear complex [(PCP)Ir]2(N2) (2), which was crystallographically characterized. We report that under N2 atmosphere the only observable nitrogen complex in solution is actually the terminal dinitrogen complex (PCP)Ir(N2). The mono- and dinuclear species are in equilibrium; the dinuclear complex more readily crystallizes from solution.
创建时间：
2006-11-06
