Insertion of SO<sub>2</sub> into a Sulfide-Bridged M−Ge Bond: Synthesis, Characterization, and Reactivity of the <i>O</i>-Germyl-<i>S</i>-sulfoxylate
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资源简介：
Addition of SO2 to (1) results in the insertion of SO2 into the Pd−Ge bond to give the O-germyl-S-sulfoxylate insertion isomer (Et3P)2Pd(μ-S)S(O)OGe[N(SiMe3)2]2 (2). Heating solutions of 2 results in the formation of (Et3P)Pd(SGe[N(SiMe3)2]2OSOGe[N(SiMe3)2]2S) (3) and a LnPd(0) fragment. X-ray crystal structures of 2 and 3 are reported.
创建时间：
2016-05-07
