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Synthesis and Reduction Kinetics of Sterically Shielded Pyrrolidine Nitroxides

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https://figshare.com/articles/dataset/Synthesis_and_Reduction_Kinetics_of_Sterically_Shielded_Pyrrolidine_Nitroxides/2476840
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A series of sterically shielded pyrrolidine nitroxides were synthesized, and their reduction by ascorbate (vitamin C) indicate that nitroxide 3, a tetraethyl derivative of 3-carboxy-PROXYL, is reduced at the slowest rate among known nitroxides, i.e., at a 60-fold slower rate than that for 3-carboxy-PROXYL.
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2016-02-20
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