Ruthenium Dihydride RuH<sub>2</sub>(PPh<sub>3</sub>)<sub>2</sub>((<i>R</i>,<i>R</i>)-cyclohexyldiamine) and Ruthenium Monohydride RuHCl(PPh<sub>3</sub>)<sub>2</sub>((<i>R</i>,<i>R</i>)-cyclohexyldiamine): Active Catalyst and Catalyst Precursor for the Hydrogenation of Ketones and Imines
收藏NIAID Data Ecosystem2026-03-06 收录
数据链接：
https://figshare.com/articles/dataset/Ruthenium_Dihydride_RuH_sub_2_sub_PPh_sub_3_sub_sub_2_sub_i_R_i_i_R_i_-cyclohexyldiamine_and_Ruthenium_Monohydride_RuHCl_PPh_sub_3_sub_sub_2_sub_i_R_i_i_R_i_-cyclohexyldiamine_Active_Catalyst_and_Catalyst_Precursor_for_the_Hydrogenation_of_Ketones_and_Imi/3762483数据链接链接失效反馈
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资源简介：
The new monohydride RuHCl(PPh3)2(R,R-cydn), with base added, and dihydride RuH2(PPh3)2(R,R-cydn), in the absence of base, catalyze the hydrogenation of a wide variety of ketones and some imines at 3 atm of H2 and 20 °C with high turnover numbers. The mechanism is thought to involve the concerted dihydrogen transfer from cis hydride and N−H groups to the substrate followed by heterolytic dihydrogen splitting.
创建时间：
2016-08-26
