Regioselective and Stepwise [8 + 2] Cycloaddition Reaction between Alkynyl–Fischer Carbene Complexes and Tropothione
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The formal [8 + 2] cycloaddition reaction between alkynyl Fischer carbene complexes and tropothione leads to the regioselective formation of novel 3aH-cyclohepta[b]thiophene carbene complexes. Computational DFT calculations indicate that the process proceeds stepwise via antiaromatic zwitterionic intermediates
创建时间:
2012-08-03



