K(NpO<sub>2</sub>)<sub>3</sub>(H<sub>2</sub>O)Cl<sub>4</sub>: A Channel Structure Assembled by Two- and Three-Center Cation–Cation Interactions of Neptunyl Cations
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A Np(V) compound containing three-center cation–cation interations, K(NpO2)3(H2O)Cl4, has been prepared by reacting Np(V) with KCl in molten boric acid. This compound forms a three-dimensional channel structure that is constructed from both two- and three-center cation–cation interactions. Three new bonding modes for cation–cation interactions are added to the summary of all known Np(V) compounds.
创建时间：
2011-06-06
