A One-Dimensional Magnet Based on [Mo<sup>III</sup>(CN)<sub>7</sub>]<sup>4–</sup>
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Self-assembly of the [MoIII(CN)7]4– anion and the MnII unit with a macrocyclic ligand results in the first example of a one-dimensional (1D) chain compound based on the heptacyanomolybdate, [Mn(LN5C10)]2[Mo(CN)7]·2H2O (LN5C10 = 1,4,7,10,13-pentaazacyclopentadecane). Because of the existence of the interchain magnetic coupling, long-rang magnetic ordering was observed in this compound.
创建时间:
2016-05-31



