Cyanide Ligand Assembly by Carbon Atom Transfer to an Iron Nitride
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https://figshare.com/articles/dataset/Cyanide_Ligand_Assembly_by_Carbon_Atom_Transfer_to_an_Iron_Nitride/5445226
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资源简介：
The
new iron(IV) nitride complex PhB(iPr2Im)3FeN reacts with 2 equiv of bis(diisopropylamino)cyclopropenylidene
(BAC) to provide PhB(iPr2Im)3Fe(CN)(N2)(BAC). This unusual example of a four-electron reaction
involves carbon atom transfer from BAC to create a cyanide ligand
along with the alkyne iPr2N–CC–NiPr2. The iron complex is in equilibrium with an
N2-free species. Further reaction with CO leads to formation
of a CO analogue, which can be independently prepared using NaCN as
the cyanide source, while reaction with B(C6F5)3 provides the cyanoborane derivative.
创建时间：
2017-09-26
