Synthetic Progress toward Azadirachtins. 2. Enantio- and Diastereoselective Synthesis of the Right-Wing Fragment of 11-epi-Azadirachtin I
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https://figshare.com/articles/dataset/Synthetic_Progress_toward_Azadirachtins_2_Enantio_and_Diastereoselective_Synthesis_of_the_Right_Wing_Fragment_of_11_i_epi_i_Azadirachtin_I/2166544
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A stereoselective three-component coupling reaction of allylzinc bromide, silyl glyoxylate, and a β-lactone has been developed. This has been successfully applied to the enantio- and diastereoselective synthesis of the fully functionalized furopyran moiety of azadirachtins.
创建时间：
2016-02-13
