A New Cyclometalation Motif: Synthesis, Structure, and Reactivity of Palladacycles That Contain a Chiral Rhenium Fragment in the Backbone and Are Catalyst Precursors for Heck Reactions
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https://figshare.com/articles/dataset/A_New_Cyclometalation_Motif_Synthesis_Structure_and_Reactivity_of_Palladacycles_That_Contain_a_Chiral_Rhenium_Fragment_in_the_Backbone_and_Are_Catalyst_Precursors_for_Heck_Reactions/3273235
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资源简介：
Reactions of (R)-[(η5-C5H5)Re(NO)(PPh3)(CH2PPh2H)]+X-, mild base, and Pd(OAc)2 yield the novel
Pd3(OAc)4-based palladacycle which has been characterized
crystallographically and elaborated to dimeric halide-bridged and monomeric palladacycles that are effective
catalyst precursors for the Heck reaction.
创建时间：
2016-05-05
