A New Cyclometalation Motif: Synthesis, Structure, and Reactivity of Palladacycles That Contain a Chiral Rhenium Fragment in the Backbone and Are Catalyst Precursors for Heck Reactions
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Reactions of (R)-[(η5-C5H5)Re(NO)(PPh3)(CH2PPh2H)]+X-, mild base, and Pd(OAc)2 yield the novel Pd3(OAc)4-based palladacycle which has been characterized crystallographically and elaborated to dimeric halide-bridged and monomeric palladacycles that are effective catalyst precursors for the Heck reaction.
创建时间：
2016-05-05
