A Two-Coordinate Manganese(0) Complex with an Unsupported Mn–Mg Bond: Allowing Access to Low Coordinate Homo- and Heterobimetallic Compounds
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https://figshare.com/articles/dataset/A_Two_Coordinate_Manganese_0_Complex_with_an_Unsupported_Mn_Mg_Bond_Allowing_Access_to_Low_Coordinate_Homo_and_Heterobimetallic_Compounds/2307262
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资源简介：
This study details the synthesis and characterization of an unprecedented
two-coordinate, high-spin manganese(0) complex that incorporates an
unsupported Mn–Mg bond, viz. L†MnMg(MesNacnac) (L† = −N(Ar†)(SiPri3), Ar† = C6H2{C(H)Ph2}2Pri-2,6,4; MesNacnac = [(MesNCMe)2CH]−; Mes = mesityl). This compound has
been utilized as an “inorganic Grignard reagent” in
the preparation of the first two-coordinate manganese(I) dimer, L†MnMnL* (L* = −N(Ar*)(SiMe3), Ar*
= C6H2{C(H)Ph2}2Me-2,6,4),
and the related mixed valence, bis(amido)-hetereobimetallic complex,
MnII(μ-L†)(μ-L*)Cr0. It is also shown to act as a two-electron reducing agent in reactions
with unsaturated substrates.
创建时间：
2016-02-17
