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A Novel Heterometallic μ9‑Boride Cluster: Synthesis and Structural Characterization of [(η5‑C5Me5Rh)2{Co6(CO)12}(μ-H)(BH)B]

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Figshare2016-02-18 更新2026-04-29 收录
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https://figshare.com/articles/dataset/A_Novel_Heterometallic_sub_9_sub_Boride_Cluster_Synthesis_and_Structural_Characterization_of_sup_5_sup_C_sub_5_sub_Me_sub_5_sub_Rh_sub_2_sub_Co_sub_6_sub_CO_sub_12_sub_H_BH_B_/2330638
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The preparation, characterization, and electronic structure of the first heterometallic μ9-boride cluster [(Cp*Rh)2{Co6(CO)12}­(μ-H)­(BH)­B)] has been reported. The interstitial boron atom in the title cluster is within the bonding contact of eight metal and one boron atom in a unique tricapped trigonal prism geometry.
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2016-02-18
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