A Novel Heterometallic μ9‑Boride Cluster: Synthesis and Structural Characterization of [(η5‑C5Me5Rh)2{Co6(CO)12}(μ-H)(BH)B]
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The preparation, characterization, and electronic structure of the first heterometallic μ9-boride cluster [(Cp*Rh)2{Co6(CO)12}(μ-H)(BH)B)] has been reported. The interstitial boron atom in the title cluster is within the bonding contact of eight metal and one boron atom in a unique tricapped trigonal prism geometry.
创建时间:
2016-02-18



