Ruthenium Catalyzed Intramolecular C–S Coupling Reactions: Synthetic Scope and Mechanistic Insight
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https://figshare.com/articles/dataset/Ruthenium_Catalyzed_Intramolecular_C_S_Coupling_Reactions_Synthetic_Scope_and_Mechanistic_Insight/2071336
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资源简介：
A ruthenium catalyzed intramolecular
C–S coupling reaction
of N-arylthioureas for the synthesis of 2-aminobenzothiazoles
has been developed. Kinetic, isotope labeling, and computational studies
reveal the involvement of an electrophilic ruthenation pathway instead
of a direct C–H activation. Stereoelectronic effect of meta-substituents
on the N-arylthiourea dictates the final regioselective
outcome of the reaction.
创建时间：
2016-02-04
