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Stereoselective Synthesis of Tetrasubstituted Alkenylboronates via 1,1-Organodiboronates

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https://figshare.com/articles/dataset/Stereoselective_Synthesis_of_Tetrasubstituted_Alkenylboronates_via_1_1_Organodiboronates/2767738
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The stereoselective synthesis of tetrasubstituted alkenylboronates was established via the lithiation/nucleophilic addition reaction of 1,1-organodiboronates to carbonyl compounds. The present approach enables the facile and practical synthesis of tetrasubstituted olefins, which are useful synthetic intermediates for further functionalizations.
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2010-05-21
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