Total Synthesis of Norbadione A<sup>†</sup>
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A short, convergent synthesis of the mushroom pigment norbadione A is described. The construction of an appropriately substituted naphtholactone intermediate involved a regioselective Diels−Alder reaction between a bis(triisopropylsilyloxy)diene and 2,6-dichlorobenzo-1,4-quinone. A double Suzuki−Miyaura cross-coupling between a diboronate and two identical enol triflates was another key feature of the synthesis.
创建时间：
2008-01-04
