AgSCF3/Na2S2O8‑Promoted Trifluoromethylthiolation/Cyclization of o‑Propargyl Arylazides/o‑Alkynyl Benzylazides: Synthesis of SCF3‑Substituted Quinolines and Isoquinolines
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A AgSCF3/Na2S2O8-promoted trifluoromethylthiolation/cascade cyclization of o-propargyl arylazides (or o-alkynyl benzylazides) triggered by a carbon–carbon triple bond is reported. This strategy provides the synthesis of valuable SCF3-substituted quinoline and isoquinoline systems via the construction of one C(sp2)–SCF3 bond and one C–N bond within one process.
创建时间：
2019-03-12
