A New 10-Connected Coordination Network with Pentanuclear Zinc Clusters as Secondary Building Units
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https://figshare.com/articles/dataset/A_New_10_Connected_Coordination_Network_with_Pentanuclear_Zinc_Clusters_as_Secondary_Building_Units/2542555
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资源简介：
An unusual 3D 10-connected metal–organic framework
[Zn5(μ3-OH)2(1,4-ndc)4(1,4-bix)2] (1, 1,4-ndc = 1,4-naphthalenedicarboxylic
acid;
1,4-bix = 1,4-bis(imidazol-1-ylmethyl)benzene) has been hydrothermally
synthesized and structurally characterized. Topological analysis indicates
that 1 is a 3D 10-connected self-penetrating framework
based on [Zn5(μ3-OH)2] pentanuclear
zinc clusters as secondary building units with the short Schläfli
symbol of 364345362. This
represents highly connected a uninodal network topology presently
known for self-penetrating systems. Moreover, the TGA and luminescence
properties of 1 were investigated.
创建时间：
2016-02-21
