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Unexpected Pt<sup>II</sup> Migration between the Calixarene Oxygen Atoms

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NIAID Data Ecosystem2026-03-06 收录
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Reaction between the 1,3-bis(trimethylsilyl) ether of calix[4]arene and platinum(II) difluoro complexes unexpectedly results in the formation of the 1,2-bridging platinum(II) calixarene complex, which, upon treatment with 2 equiv of acyl chloride, reinstates the 1,3-disubstitution pattern in the calixarene moiety.

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2016-03-01
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