[60]Fullerene as a Versatile Four-Electron Donor Ligand
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https://figshare.com/articles/dataset/_60_Fullerene_as_a_Versatile_Four-Electron_Donor_Ligand/3770796
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资源简介：
A new 1,2-σ-type C60 compound, Os3(CO)7(CNR)(μ3-CNR)(PPh3)(μ3-η1:η1:η2-C60) (2; R = CH2Ph),
is formed from Os3(CO)8(CNR)(μ3-CNR)(μ3-η1:η2:η1-C60)
(1) upon substitution of CO with PPh3 on a triosmium
cluster framework. Compounds 1 and 2 are reversibly
interconvertible. Further reaction of 2 with PPh3 results
in a π-type C60 complex, Os3(CO)6(CNR)(μ3-CNCH2C6H4)(PPh3)(μ-PPh2)(μ-η2:η2-C60) (3), with an Os−Os bond
cleavage.
创建时间：
2016-08-26
