Construction of the Azacyclic Core of Tabernaemontanine-Related Alkaloids <i>via</i> Tandem Reformatsky–Aza-Claisen Rearrangement
收藏NIAID Data Ecosystem2026-03-10 收录
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A divergent synthetic methodology for a tabernaemontanine-related alkaloid was developed. The synthetic route features practical improvements in the Pictet–Spengler cyclization for the tetrahydro-β-carboline intermediate and an unprecedented tandem Reformatsky–aza-Claisen rearrangement to create the core carbon skeleton and stereochemistries of tabernaemontanine-related alkaloids.
创建时间：
2017-01-19
