A Helix−Turn−Helix Supersecondary Structure Based on Oligo(phenanthroline dicarboxamide)s
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An artificial helix−turn−helix (HTH) supersecondary structure based on the oligo(phenanthroline dicarboxamide)s, in which the 2,2‘-dimethoxy-1,1‘-binaphthyl-6,6‘-diamine subunit was utilized as the turn to impart a bias in the twist sense of the supersecondary structure, was reported. The HTH structure has been demonstrated by UV/vis, NMR, CD spectra, and X-ray crystal analysis.
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2016-06-03
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