Annulation of Indole-2-Carboxamides with Bicycloalkenes Catalyzed by Ru(II) at Room Temperature: An Easy Access to β‑Carboline-1-one Derivatives under Mild Conditions
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https://figshare.com/articles/dataset/Annulation_of_Indole-2-Carboxamides_with_Bicycloalkenes_Catalyzed_by_Ru_II_at_Room_Temperature_An_Easy_Access_to_Carboline-1-one_Derivatives_under_Mild_Conditions/21828204
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资源简介：
Herein, we report the annulation
of indole-2-carboxamides
with
bicycloalkenes, to synthesize β-carboline-1-one derivatives
under mild conditions. The commercially available ruthenium catalyst
was used for the reaction. This reaction tolerates a wide range of
functional groups and affords a good yield of β-carboline-1-one
derivatives. A reversible cyclometalation pathway was found to be
operative in the mechanistic study.
创建时间：
2023-01-06
