Synthesis of a Tertiary Carbinamide via a Novel Rh-Catalyzed Asymmetric Hydrogenation
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https://figshare.com/articles/dataset/Synthesis_of_a_Tertiary_Carbinamide_via_a_Novel_Rh_Catalyzed_Asymmetric_Hydrogenation/2957353
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资源简介：
Asymmetric hydrogenation of allylic dimethylcarbinamide
2 with 1 mol % of cationic Rh(I)−Josiphos complex in THF
under 500 psi of H2 generated the corresponding tertiary
carbinamide 1 in 98.5% assay yield and a 94:6 enantiomeric
ratio. Upon crystallization, the product was isolated in 91%
isolated yield and 95:5 enantiomeric ratio.
创建时间：
2016-06-03
