Enantioselective and Solvent-Controlled Diastereoselective Mannich Reaction of Isatin Imines with Hydroxyacetone: Synthesis of 3-Substituted 3-Aminooxindoles
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https://figshare.com/articles/dataset/Enantioselective_and_Solvent_Controlled_Diastereoselective_Mannich_Reaction_of_Isatin_Imines_with_Hydroxyacetone_Synthesis_of_3_Substituted_3_Aminooxindoles/2533207
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资源简介：
The diastereoselectively switchable enantioselective
Mannich reaction of isatin imines with hydroxyacetone is reported.
The chiral primary amino acid catalyzed this Mannich reaction to afford
both anti- and syn-Mannich adducts
in high yields, good diastereoselectivities, and enantioselectivities.
The reason for the solvent control of the diastereoselectivity phenomenon
was investigated.
创建时间：
2016-02-21
