Conformational Preferences of a Polar Biaryl: A Phase- and Enantiomeric Purity-Dependent Molecular Hinge
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https://figshare.com/articles/dataset/Conformational_Preferences_of_a_Polar_Biaryl_A_Phase_and_Enantiomeric_Purity_Dependent_Molecular_Hinge/2852647
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资源简介：
The favored (RS*,M*) diastereoisomer of 2-aryl-pyridine 1 in the solution state results from intramolecular dipole−dipole interactions. In the crystalline state, intermolecular interactions dominate, and the conformation switches reversibly to (RS*,P*). Only racemic 1 exhibits this switching property: enantiomerically pure 1 exists as the (RS*,M*) diastereoisomer in both the solution and crystalline state.
创建时间：
2016-02-26
