Bis[tetraruthenium(IV)]-Containing Polyoxometalates: [{Ru<sup>IV</sup><sub>4</sub>O<sub>6</sub>(H<sub>2</sub>O)<sub>9</sub>}<sub>2</sub>Sb<sub>2</sub>W<sub>20</sub>O<sub>68</sub>(OH)<sub>2</sub>]<sup>4–</sup> and [{Ru<sup>IV</sup><sub>4</sub>O<sub>6</sub>(H<sub>2</sub>O)<sub>9</sub>}<sub>2</sub>{Fe(H<sub>2</sub>O)<sub>2</sub>}<sub>2</sub>{β-TeW<sub>9</sub>O<sub>33</sub>}<sub>2</sub>H]<sup>−</sup>
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数据链接：
https://figshare.com/articles/dataset/Bis_tetraruthenium_IV_Containing_Polyoxometalates_Ru_sup_IV_sup_sub_4_sub_O_sub_6_sub_H_sub_2_sub_O_sub_9_sub_sub_2_sub_Sb_sub_2_sub_W_sub_20_sub_O_sub_68_sub_OH_sub_2_sub_sup_4_sup_and_Ru_sup_IV_sup_sub_4_sub_O_sub_6_sub_H_sub_2_sub_O_sub_9_sub_sub_2_sub/2505271数据链接链接失效反馈
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资源简介：
The reaction of [Sb2W22O74(OH)2]12– and [Fe4(H2O)10(β-TeW9O33)2]4– with (NH4)2[RuCl6] in aqueous solution resulted in the novel ruthenium(IV)-containing polyanions [{RuIV4O6(H2O)9}2Sb2W20O68(OH)2]4– and [{RuIV4O6(H2O)9}2{Fe(H2O)2}2{β-TeW9O33}2H]−, exhibiting two cationic, adamantane-like, tetraruthenium(IV) units {Ru4O6(H2O)9}4+ bound to the respective polyanion in an external, highly accessible fashion.
创建时间：
2016-02-20
