Influence of Framework n(Si)/n(Al) Ratio on the Nature of Cu Species in Cu-ZSM-5 for NH3-SCR-DeNOx

<strong>Data type</strong>: Experimental spectroscopic measurements, computer simulation and analysis Files are with filename extensions: <strong>DSC</strong>, <strong>DAT</strong>, <strong>m</strong>, <strong>txt</strong> Information on <strong>origin of the data</strong>: EPR spectroscopic measurements with filename extensions <strong>DSC</strong>, <strong>DTA.</strong> EPR spectroscopic simulation and analyses with filename extension <strong>m</strong>. EPR spectra are exported as <strong>txt</strong> files in ASCII format. X-band CW-EPR spectroscopic measurements were generated by EMX spectrometer equipped with SHQ cavity produced by Bruker. <strong>If the dataset includes multiple files that relate to each other:</strong> Files in <strong>PARACAT_WP3_20220705_01_CW_Experimental</strong> folder includes X-band CW-EPR spectroscopic measurements; original data are in DTA/DSC and txt formats. Files in <strong>PARACAT_WP3_20220705_02_CW_Simulations</strong> folder includes computer simulations/analyses of the EPR measurements; data are in m and txt formats. <strong>Information on</strong>: specialized abbreviations: <strong>EPR</strong> – Electron Paramagnetic Resonance, <strong>CW</strong> – Continuous Wave EPR, <strong>exp </strong>– experimental data, <strong>hyd </strong>– cw-EPR spectra related to hydrated state, <strong>dehyd </strong>– cw-EPR spectra related to the dehydrated state, <strong>sim </strong>– simulation data. <strong>Sys </strong>– copper species used for constructing the spin-Hamiltonian in EPR simulations. <strong>Cu-ZSM-5-com </strong>– commercial Cu-ZSM-5. <strong>Cu-ZSM-5-100</strong> – Cu-ZSM-5 synthesized at 100 °C. <strong>Cu-ZSM-5-120</strong> – Cu-ZSM-5 synthesized at 120 °C. <strong>Cu-ZSM-5-150</strong> – Cu-ZSM-5 synthesized at 150 °C. – Cu-ZSM-5 synthesized at 170 °C. definitions of variables: <strong>Magnetic field, Temperature.</strong> units of measurement: <strong>Gauss (G), K, degree (°), milliTesla (mT)</strong>.