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Biphenylene-4,4‘-diselenolate as a Molecular Bridge: Preparation and Characterization of [PdCl(P<i>n</i>Bu<sub>3</sub>)<sub>2</sub>Se-C<sub>6</sub>H<sub>4</sub>-C<sub>6</sub>H<sub>4</sub>-Se-PdCl(P<i>n</i>Bu<sub>3</sub>)<sub>2</sub>]

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Biphenylene-4,4‘-dilithiodiselenolate or biphenylene-4,4‘-bis(trimethylsilylselenium) can be used to prepare the complex [PdCl(PnBu3)2SeC6H4C6H4SePdCl(PnBu3)2]. The dimer contains two trans-MCl(Se−)(PBu3)2 metal centers separated by a planar biphenylene moiety.

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2016-05-06
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