Construction of Erythrinane Skeleton via Pd(0)-Catalyzed Intramolecular Dearomatization of <i>para</i>-Aminophenols
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A novel Pd(0)-catalyzed intramolecular arylative dearomatization of para-aminophenol derivatives is described. In the presence of 1.25 mol % [Pd(C3H5)Cl]2 and 3.75 mol % RuPhos, the arylative dearomatization reaction proceeds smoothly for a broad range of substrates, offering an efficient synthetic route to erythrinane derivatives in excellent yields.
创建时间：
2014-11-05
