A Photochemical One-Pot Three-Component Synthesis of Tetrasubstituted Imidazoles
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https://figshare.com/articles/dataset/A_Photochemical_One_Pot_Three_Component_Synthesis_of_Tetrasubstituted_Imidazoles/2244343
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资源简介：
Tetrasubstituted
imidazoles can be formed in a photochemical one-pot
synthesis from aldehydes, α-aminonitriles, and isoxazoles. Condensation
of the first two components produces α-(alkylideneamino)nitriles
which react under basic conditions with the acylazirines formed in
situ by photochemical ring transformation of the isoxazole component.
This process includes an unusual cleavage of the C2–C3 bond of the acylazirine. The reaction mechanism was studied
by DFT calculations.
创建时间：
2016-02-16
