Rhodium-Catalyzed Oxidative Annulation of Hydrazines with Alkynes Using a Nitrobenzene Oxidant
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https://figshare.com/articles/dataset/Rhodium_Catalyzed_Oxidative_Annulation_of_Hydrazines_with_Alkynes_Using_a_Nitrobenzene_Oxidant/2228437
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资源简介：
Rhodium-catalyzed
oxidative annulation of hydrazines with alkynes
has been accomplished using 1,3-dinitrobenzene as an oxidant. A variety
of hydrazines with alkynes were converted to 1-aminoindole derivatives
in good to high yields. Mechanistic investigations support the idea
that 1,3-dinitrobenzene serves as the oxidant during C–H activation.
This is, to our knowledge, the first report of a nitrobenzene compound
used as the oxidant in transition-metal-catalyzed C–H activation.
创建时间：
2016-02-16
