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Diarylborenium Cations: Synthesis, Structure, and Electrochemistry

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Mes2BF and ArN2BF (ArN = 4-(Me2N)-2,6-Me2-C6H2) react with trimethylsilyltriflate and p-dimethylaminopyridine in chlorobenzene to afford the corresponding borenium salts [Mes2B-DMAP]+ OTf− ([1]+OTf−) and [ArN2B-DMAP]+ OTf− ([2]+OTf−), which have been fully characterized.

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2008-04-14
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