Novel Layered Ruthenium Diphosphonate Containing a Mixed Valent Diruthenium Paddlewheel Core
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https://figshare.com/articles/dataset/Novel_Layered_Ruthenium_Diphosphonate_Containing_a_Mixed_Valent_Diruthenium_Paddlewheel_Core/4057215
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资源简介:
This paper reports the synthesis and crystal structure of a novel
mixed valence ruthenium(II,III) compound, (NH4)3Ru2(hedp)2·2H2O
(1), where hedp represents 1-hydroxyethylidenediphosphonate. It
has a two-dimensional structure in which the paddlewheel
diruthenium(II,III) units of Ru2(hedp)2 are cross-linked through the
phosphonate groups. The layers are stacked along the [100]
direction with strong intra- and interlayer hydrogen bonds. Primary
magnetic results are presented.
创建时间:
2016-10-25



