Rearrangement of Pyridine to Its 2-Carbene Tautomer Mediated by Iridium
收藏NIAID Data Ecosystem2026-03-06 收录
下载链接：
https://figshare.com/articles/dataset/Rearrangement_of_Pyridine_to_Its_2_Carbene_Tautomer_Mediated_by_Iridium/2973625
下载链接
链接失效反馈官方服务：
资源简介：
One of the Ir−CH2 bonds within the chelate structure of compound 1 acts as a C−H activation shuttle and permits the 1,2-H shift needed for the isomerization of pyridine to its 2-carbene tautomer. The iridium-mediated tautomerization is kinetically competitive with traditionally facile N coordination of the heterocycle.
创建时间：
2016-02-28
