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Synthesis and Reactivity of Silyl Vinylketenes: A Formal Interrupted Dötz Benzannulation with Unexpected Silyl Migration

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NIAID Data Ecosystem2026-03-06 收录
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https://figshare.com/articles/dataset/Synthesis_and_Reactivity_of_Silyl_Vinylketenes_A_Formal_Interrupted_D_tz_Benzannulation_with_Unexpected_Silyl_Migration/3740331
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资源简介:
An efficient method for the generation of silyl vinylketenes from the thermal reaction of Fischer carbene complexes with silyl-substituted phenylacetylenes is described. Although the silyl vinylketene products are highly stable, conditions have been identified to induce a benzannulation/silyl migration process, providing aromatic silyl ethers.
创建时间:
2016-08-20
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