A Chemically-Driven Molecular Information Ratchet
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https://figshare.com/articles/dataset/A_Chemically_Driven_Molecular_Information_Ratchet/2957914
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资源简介：
A chemically driven molecular information ratchet is described. The equilibrium macrocycle distribution in a [2]rotaxane is driven away from its 50:50 population of thread binding sites to a 33:67 ratio by benzoylation under the influence of a chiral catalyst. The reaction corresponds to a dynamic kinetic resolution of rotaxane co-conformers that interconvert through shuttling.
创建时间：
2016-06-03
