A Chemically-Driven Molecular Information Ratchet
收藏NIAID Data Ecosystem2026-03-06 收录
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A chemically driven molecular information ratchet is described. The equilibrium macrocycle distribution in a [2]rotaxane is driven away from its 50:50 population of thread binding sites to a 33:67 ratio by benzoylation under the influence of a chiral catalyst. The reaction corresponds to a dynamic kinetic resolution of rotaxane co-conformers that interconvert through shuttling.
创建时间：
2016-06-03
