Mesoionic 1,3-Oxazinium Olates. Rearrangement to Acylketenes and 3-Azabicyclo[3.1.1]heptanetriones
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https://figshare.com/articles/dataset/Mesoionic_1_3_Oxazinium_Olates_Rearrangement_to_Acylketenes_and_3_Azabicyclo_3_1_1_heptanetriones/3276109
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资源简介：
Metastable but isolable mesoionic 1,3-oxazinium 4-olates 9d−f undergo ring opening to acylketenes
10 at or near room temperature. The ketenes undergo intramolecular criss-cross [2 + 2] cycloaddition
to afford 3-azabicyclo[3.1.1]heptanetriones 12. The structure of 12d was established by X-ray
crystallography.
创建时间：
2016-05-05
