Breaking Zachariasen rules - the structure of barium zirconium fluoride glasses

Glass is an essential material with applications that are dominated by oxides, but fluoride glasses (based on barium zirconium fluorides, "ZBLAN" glasses) have key applications...玻璃是一类至关重要的材料，其应用场景中占主导地位的为氧化物基玻璃，但以氟锆酸钡为基础的氟化物玻璃（即"ZBLAN"玻璃）却拥有关键的应用……