Exploratory Synthesis in Molten Salts: Role of Flux Basicity in the Stabilization of the Complex Thiogermanates Cs<sub>4</sub>Pb<sub>4</sub>Ge<sub>5</sub>S<sub>16</sub>, K<sub>2</sub>PbGe<sub>2</sub>S<sub>6</sub>, and K<sub>4</sub>Sn<sub>3</sub>Ge<sub>3</sub>S<sub>14</sub>
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数据链接：
https://figshare.com/articles/dataset/Exploratory_Synthesis_in_Molten_Salts_Role_of_Flux_Basicity_in_the_Stabilization_of_the_Complex_Thiogermanates_Cs_sub_4_sub_Pb_sub_4_sub_Ge_sub_5_sub_S_sub_16_sub_K_sub_2_sub_PbGe_sub_2_sub_S_sub_6_sub_and_K_sub_4_sub_Sn_sub_3_sub_Ge_sub_3_sub_S_sub_14_su/3282244数据链接链接失效反馈
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资源简介：
The influence of the Lewis basicity of alkali polysulfide fluxes (A2Sx) (A = alkali) as a function of x on the respective reactivities of Pb and Sn with Ge was studied and found to be strong. Cs4Pb4Ge5S16, K2PbGe2S6, and K4Sn3Ge3S14 could be prepared only under low basicity with S/A2S ratios of ≥11. These compounds display complex frameworks and are semiconductors. Cs4Pb4Ge5S16 is luminescent with red emission.
创建时间：
2016-05-06
