Supporting data for 'Toward Advanced Interfacial Materials: Role of Molecular Topology Elucidated in Unified Gels and Hydrolysis-Controlled Porous Polymeric Particles'

This thesis reports the findings of two main research projects. The raw and processed data related to these studies are included in this dataset.The first project involved the development of a unified gel system. This system incorporates molecular isomers and analogues with distinct topological structures, enabling direct cross-system comparisons to clarify how topology regulates the material's mechanical and dynamic properties. Supporting data from NMR spectroscopy, mechanical tests, viscoelastic measurements, and DFT simulations are presented.The subsequent project developed an efficient emulsion-templating method for synthesizing porous polymer particles. By controlling the hydrolysis of an amphiphilic block copolymer (PS-b-PGMA), this approach allows for the preparation of porous particles with tunable size, surface roughness, pore size, open/closed porosity, and internal cavity structure during emulsion self-assembly. Supporting data from NMR spectroscopy, SEM, and TEM are provided.