Base-Promoted, Aerobic, and Regioselective Carbon–Hydrogen Bond Activation of Thiophene with Group 9 Metalloporphyrins
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https://figshare.com/articles/dataset/Base-Promoted_Aerobic_and_Regioselective_Carbon_Hydrogen_Bond_Activation_of_Thiophene_with_Group_9_Metalloporphyrins/3858834
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资源简介：
Base-promoted aerobic
carbon–hydrogen bond activation (CHA)
of thiophene was achieved with high regioselectivity at the 2-position
by group 9 metalloporphyrins in moderate to high yields. Mechanistic
investigations suggest a homolytic aromatic substitution through MII(ttp) (M = Rh, Ir) metalloradical addition, followed by β-elimination
of a metal hydride pathway.
创建时间：
2016-10-04
