SUPPORTING INFORMATION FOR: Highly Regioselective Synthesis of Bio-based Hydroxyurethanes
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The regioselective synthesis of carbamates from bio-derived cyclic carbonates and amines by using 1,5,7-triazabicyclo[4.4.0]dec-5-ene as an organocatalyst is reported. This methodology led to the preparation of a wide range of bio-sourced hydroxyurethanes from furan-, carvone- and limonene-based scaffolds under solvent-free and mild reaction conditions. Moreover, a comprehensive analysis of the process allowed us to optimize the catalyst loading with little or no impact on the process regioselectivity.
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Zenodo创建时间：
2025-02-17
