Synthesis of [Pt(SnBut3)(IBut)(μ-H)]2, a Coordinatively Unsaturated Dinuclear Compound which Fragments upon Addition of Small Molecules to Form Mononuclear Pt–Sn Complexes
收藏Figshare2016-12-16 更新2026-04-29 收录
下载链接：
https://figshare.com/articles/dataset/Synthesis_of_Pt_SnBu_sup_t_sup_sub_3_sub_IBu_sup_t_sup_H_sub_2_sub_a_Coordinatively_Unsaturated_Dinuclear_Compound_which_Fragments_upon_Addition_of_Small_Molecules_to_Form_Mononuclear_Pt_Sn_Complexes/2092480
下载链接
链接失效反馈官方服务：
资源简介：
The reaction of Pt(COD)2 with one equivalent of tri-tert-butylstannane, But3SnH, at room temperature yields Pt(SnBut3)(COD)(H)(3) in quantitative yield. In the presence of excess But3SnH, the reaction goes further, yielding the dinuclear bridging stannylene complex [Pt(SnBut3)(μ-SnBut2)(H)2]2 (4). The dinuclear complex 4 reacts rapidly and reversibly with CO to furnish [Pt(SnBut3)(μ-SnBut2)(CO)(H)2]2 (5). Complex 3 reacts with N,N′-di-tert-butylimidazol-2-ylidene, IBut, at room temperature to give the dinuclear bridging hydride complex [Pt(SnBut3)(IBut)(μ-H)]2 (6). Complex 6 reacts with CO, C2H4, and H2 to give the corresponding mononuclear Pt complexes Pt(SnBut3)(IBut)(CO)(H)(7), Pt(SnBut3)(IBut)(C2H4)(H)(8), and Pt(SnBut3)(IBut)(H)3 (9), respectively. The reaction of IBut with the complex Pt(SnBut3)2(CO)2 (10) yielded an abnormal Pt-carbene complex Pt(SnBut3)2(aIBut)(CO) (11). DFT computational studies of the dimeric complexes [Pt(SnR3)(NHC)(μ-H)]2, the potentially more reactive monomeric complexes Pt(SnR3)(NHC)(H) and the trihydride species Pt(SnBut3)(IBut)(H)3 have been performed, for NHC = IMe and R = Me and for NHC = IBut and R = But. The structures of complexes 3–8 and 11 have been determined by X-ray crystallography and are reported.
创建时间：
2016-12-16
